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Beilstein J. Org. Chem. 2019, 15, 752–760, doi:10.3762/bjoc.15.71
Graphical Abstract
Scheme 1: Various strategies leading to the formation of cyclopropanols.
Scheme 2: General approach to the preparation of cyclopropanol and cyclopropylamine derivatives.
Figure 1: Prerequisite for a regio- and diastereoselective carbometalation.
Scheme 3: Preparation of cyclopropenyl methyl ethers 3a–d.
Scheme 4: Regio- and diastereoselective carbocupration of cyclopropenyl methyl ethers 3a,c.
Scheme 5: Diastereoselective formation of cyclopropanols.
Scheme 6: Diastereoselective carbometalation/oxidation of nonfunctionalized cyclopropenes 6.
Scheme 7: Preparation of diastereoisomerically pure and enantioenriched cyclopropanols and cyclopropylamines.